Product ID:UNDERCOATS, 4501 BODY SHIELD
MSDS Date:09/01/1992
FSC:8010
NIIN:00N064614
MSDS Number: BZQDG

MARTIN-SENOUR CO

101 PROSPECT AVE NW
CLEVELAND, OH 44115
US

Emergency Phone: 216-566-2917

Info Phone: 216-566-2902

Cage: 16772

MARTIN-SENOUR CO THE DIV SHERWIN-WILLIAMS CO

CHICAGO, IL 60608-5724 US

Cage: 16772

127

CAS: 110-54-3

RTECS: MN9275000

Fraction By Weight: 37%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

KEROSENE (PETROLEUM), HYDROTREATED; (MINERAL SPIRITS) VP

CAS: 64742-47-8

RTECS: OA5504000

Fraction By Weight: 5%

OSHA PEL 100 PPM (MFR)

ACGIH TLV: 100 PPM (MFR)

22

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 9%

OSHA PEL 200 PPM

ACGIH TLV: 50 PPM, S

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

5.9

CAS: 1330-20-7

RTECS: ZE2100000

Fraction By Weight: 31%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM; 150 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

92

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 1%

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM; 250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

ASPHALT; (ASPHALT (PETROLEUM)

CAS: 8052-42-4

RTECS: CI9900000

Fraction By Weight: 11%

OSHA PEL 5 MG/M3 (MFR)

ACGIH TLV: 5 MG/M3 (FUME)

SILICA, CRYSTALLINE - QUARTZ; (QUARTZ) (MFR'S CAS

CAS: 14808-60-7

RTECS: VV7330000

Fraction By Weight: 0.4%

OSHA PEL N/K

ACGIH TLV: 0.1 MG/M3 RDUST

ALUMINOSILICATE

CAS: 1327-36-2

Fraction By Weight: 3%

OSHA PEL 10MG/M3 RDUST (MFR)

ACGIH TLV: 10MG/M3 RDUST (MFR)

1); (CALCIUM CARBONATE)

CAS: 471-34-1

RTECS: FF9335000

Fraction By Weight: 8%

OSHA PEL 15 MG/M3 RDUST (MFR)

ACGIH TLV: 10 MG/M3 RDUST (MFR)

VOLATILE ORGANIC COMPOUND - TOTAL AND LESS WATER AND EXEMPT

RTECS: 9999999VO

OSHA PEL N/K

ACGIH TLV: N/K

ANIMAL STUDIES W/POOR CTLS INDICATED

RTECS: 9999999ZZ

EVID THAT BITUMENS ALONE ARE CARCIN TO HUMANS.

RTECS: 9999999ZZ

TISS OF ARMS & LEGS (PERIPHERAL NEUROPATHY), RSLTG

RTECS: 9999999ZZ

BY PRESENCE OF METHYL ETHYL KETONE. PRLNGD OVEREXP

RTECS: 9999999ZZ

LIVER, URINARY, BLOOD FORMING, CVS & REPRO SYS. RPTS

RTECS: 9999999ZZ

BRAIN & NERVOUS SYS DMG. INTENTIONAL MISUSE BY

RTECS: 9999999ZZ

& HEATERS. TURN OFF STOVES, ELEC TOOLS &

RTECS: 9999999ZZ

NFPA CODE. USE APPRVD BONDING & GROUNDING PROCS.

RTECS: 9999999ZZ

APPRVD CNTNRS W/COMPLETE & APPROP LABELING. DO NOT

RTECS: 9999999ZZ

DUSTS ARE LISTED, APPLIC LIMS FOR NUISANCE

RTECS: 9999999ZZ

(TDUST), 5 MG/M3 (RESPIRABLE FRACTION).

RTECS: 9999999ZZ

GENERATED FROM THIS PRODUCT, UNDERLYING PAINT OR

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:ACUTE: IRRIT OF EYES, SKIN & RESP SYS.
MAY CAUSE NERVOUS SYS DEPRESS. EXTREME OVEREXP MAY RSLT IN UNCON &
POSS DEATH. HDCH, DIZZ, NAUS & LOSS OF COORDINATION ARE INDICATIONS
OF EXCESS EXPOS TO VAPS/SP RAY MISTS. REDNESS & ITCH OR BURNING
SENSATION MAY INDICATE EYE/EXCESS SKIN EXPOS. CHRONIC: TOLUENE
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:SILICA, CRYSTALLINE-QUARTZ: IARC MONO,
SUPP, VOL 7, PG 341, 1987:GROUP 2A. NTP 7TH ANNUAL REPORT ON
CARCINS, (SUPDAT)
Effects of Overexposure:HLTH HAZ: APPEARS ON NAVY OCCUP CHEM REPRO HAZS
LIST. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS CONCERNING
LATEST HAZ LIST INFO & SAFE HNDLG & EXPOS INFO . LONG TERM EXPOS TO
HIGH LEVELS OF SILICA DUST WHICH CAN OCCUR ONLY WHEN
SANDING/ABRADING DRIED FILM, MAY CAUSE LUNG DMG (SILICOSIS). SOME
(ING 11)
Medical Cond Aggravated by Exposure:NONE GENERALLY RECOGNIZED.

First Aid:INHAL: REMOVE FROM EXPOSURE. RESTORE BREATHING. KEEP WARM AND
QUIET. SKIN: WASH AFFECTED AREA THOROUGHLY WITH SOAP AND WATER.
REMOVE CONTAMINATED CLOTHING AND LUANDER BEFORE REUSE. EYES: FLUSH
EYES WI TH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. GET
MEDICAL ATTENTION. INGEST: SEEK MEDICAL ATTENTION.

Flash Point:56.0F,13.3C
Lower Limits:1.0%
Upper Limits:7.0%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
WATER SPRAY MAY BE INEFTIVE. IF WATER IS USED, FOG NOZZS ARE PREF.
WATER MAY BE USED TO COOL CLSD (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP CNTNRS TIGHTLY CLSD. ISOLATE FROM
HEAT, ELEC EQUIP, SPKS & OPEN FLAME. CLSD CNTNRS MAY EXPLODE WHEN
EXPOS TO EXTREME HEAT. APPLICATN TO HOT SURFS (SUPDAT)

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. VENTILATE AND
REMOVE WITH INERT ABSORBENT.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPKS & OPEN
FLAME. DURING USE & UNTIL ALL VAPS ARE GONE: KEEP AREA VENT. DO NOT
SMOKE. EXTING ALL FLAMES, PILOT LIGHTS (ING 17)
Other Precautions:USE ONLY W/ADEQ VENT. AVOID BRTHG VAP & SPRAY MIST.
AVOID CNTCT W/SKIN & EYES. COATING MAY CNTN MATLS CLASSIFIED AS
NUISANCE PARTICULATES WHICH MAY BE PRESENT AT HAZ LEVELS ONLY
DURING SANDING/ABRADIN G OF DRIED FILM. IF NO SPECIFIC (ING 20)

Respiratory Protection:IF PERSONAL EXPOS CANNOT BE CONTROLLED BELOW
APPLIM LIMS VY VENT, WEAR NIOSH/MSHA APPRVD, PROPERLY FITTED ORG
VAP/PARTICULATE RESP. WHEN SANDING/ABRADING DRIED FILM, WEAR
DUST/MIST RESP APPRVD BY NIOS H/MSHA FOR DUSTS WHICH MAY BE (ING
22)
Ventilation:LOC EXHST PREF. GEN EXHST ACCEPTABLE IF EXPOS IS MAINTAINED
BELOW APPLIC EXPOS LIMS. REFER TO OSHA STDS 1910.94,107,108.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
Work Hygienic Practices:WASH HANDS AFTER USING.
Supplemental Safety and Health
FIRE FIGHT PROC: CNTNRS TO PVNT PRESS BUILD-UP & POSS AUTOIGNIT/EXPLOS
WHEN EXPOSED TO EXTREME HEAT. EXPLO HAZ: REQS SPEC PRECS. DURING
EMER CNDTNS OVEREXP TO DECOMP PRODS MAY CAUSE HLTH HAZ. SYMPS MA Y
NOT BE IMMED APPARENT. OBTAIN MED ATTN. EXPLAN OF CARCIN:
1994:ANTIC TO BE CARCIN. ANIMAL:LUNG.

Boiling Pt:B.P. Text:>142F,>61C
Vapor Pres:SEE INGS
Vapor Density:HVR/AIR
Spec Gravity:0.90-0.99
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:NONE SPECIFIED BY MANUFACTURER.
Percent Volatiles by Volume:>70

Stability Indicator/Materials to Avoid:YES
NONE KNOWN.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BY FIRE: CARBON DIOXIDE, CARBON
MONOXIDE.

Waste Disposal Methods:WASTE FROM PROD MAY BE HAZ AS DEFINED UNDER RCRA
40 CFR 261. WASTE MUST BE TESTED FOR IGNITABILITY TO DETERM APPLIC
EPA HAZ WASTE NUMBERS. INCIN IN APPRVD FACILITY. DO NOT INCIN CLSD
CNTNRS. DISPOSE O F I/A/W FED, STATE & LOC REGS REGARDINGPOLLUTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.